State Features and Fluorescence of N,N'-Bis(5-bromosalicylidene)-1,3-propylenediamine in a Perfluorosulfonic Membrane


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In the process of N,N'-bis(5-bromosalicylidene)-1,3-propylenediamine sorption by a perfluorosulfonic membrane donor-acceptor interaction of azomethine with membrane sulfo groups appears as considerable simultaneous shifts of absorption and fluorescence spectra compared to analogous azomethine spectra in alcohol solutions. An analysis of the observed changes suggests that the π*N=C antibonding states of the azomethine molecule fragment are emitting.

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V. Pak

Herzen State Pedagogical University of Russia

编辑信件的主要联系方式.
Email: pakviacheslav@mail.ru
俄罗斯联邦, nab. reki Moiki 48, St. Petersburg, 191186

N. Lapatin

Herzen State Pedagogical University of Russia

Email: pakviacheslav@mail.ru
俄罗斯联邦, nab. reki Moiki 48, St. Petersburg, 191186

A. Borisov

Herzen State Pedagogical University of Russia

Email: pakviacheslav@mail.ru
俄罗斯联邦, nab. reki Moiki 48, St. Petersburg, 191186

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