Мақаланы E-mail арқылы жіберу Complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs)
- Авторлар: Chernysheva A.M.1, Shelyganov P.A.1, Kazakov I.V.1, Timoshkin A.Y.1
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Мекемелер:
- St. Petersburg State University
- Шығарылым: Том 87, № 4 (2017)
- Беттер: 665-669
- Бөлім: Article
- URL: https://bakhtiniada.ru/1070-3632/article/view/219136
- DOI: https://doi.org/10.1134/S1070363217040016
- ID: 219136
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Аннотация
Structural, spectral, and thermodynamic characteristics of complex amidoboranes M2[M1(NH2BH3)4] (M1 = Al, Ga; M2 = Li, Na, K, Rb, Cs) were calculated by the B3LYP/def2-SVPD quantum-chemical method. The procedure for the synthesis of these compounds by reactions of alkali metal amidoboranes with aluminum and gallium chlorides was suggested and experimentally tested. Reaction products were characterized by the NMR and IR spectroscopy and X-ray phase analysis.
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Авторлар туралы
A. Chernysheva
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Ресей, Universitetskaya nab. 7–9, St. Petersburg, 199034
P. Shelyganov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Ресей, Universitetskaya nab. 7–9, St. Petersburg, 199034
I. Kazakov
St. Petersburg State University
Email: a.y.timoshkin@spbu.ru
Ресей, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. Timoshkin
St. Petersburg State University
Хат алмасуға жауапты Автор.
Email: a.y.timoshkin@spbu.ru
Ресей, Universitetskaya nab. 7–9, St. Petersburg, 199034
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