Synthesis, structure, and photoluminescence properties of N-{2-[5-(2-hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methylbenzenesulfamides and their zinc complexes


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N-{2-[5-(2-Hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methyl-benzenesulfamides (H2L) and their zinc complexes Zn2L2 were synthesized. The structure of the ligands and complexes was studied by IR, UV, 1Н NMR, X-ray absorption spectroscopy, and X-ray diffraction analysis. The complexes show green photoluminescence (λfl = 492 nm) with quantum yields φ = 0.07–0.17.

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Yu. Koshchienko

Institute of Physical and Organic Chemistry of Southern Federal University

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, pr. Stachki 194/2, Rostov-on-Don, 344090

A. Burlov

Institute of Physical and Organic Chemistry of Southern Federal University

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Email: anatoly.burlov@yandex.ru
俄罗斯联邦, pr. Stachki 194/2, Rostov-on-Don, 344090

N. Makarova

Institute of Physical and Organic Chemistry of Southern Federal University

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, pr. Stachki 194/2, Rostov-on-Don, 344090

V. Vlasenko

Institute of Physics of Southern Federal University

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, Rostov-on-Don

S. Nikolaevskii

N.S. Kurnakov Institute of General and Inorganic Chemistry

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, Moscow

M. Kiskin

N.S. Kurnakov Institute of General and Inorganic Chemistry

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, Moscow

G. Alexandrov

N.S. Kurnakov Institute of General and Inorganic Chemistry

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, Moscow

D. Garnovskii

Southern Scientific Centre Academy of Sciences

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, Rostov-on-Don

A. Metelitsa

Institute of Physical and Organic Chemistry of Southern Federal University

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, pr. Stachki 194/2, Rostov-on-Don, 344090

V. Minkin

Institute of Physical and Organic Chemistry of Southern Federal University

Email: anatoly.burlov@yandex.ru
俄罗斯联邦, pr. Stachki 194/2, Rostov-on-Don, 344090

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