Synthesis of azidooxetane statistical polymers and copolymers


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Statistical polymers and copolymers were firstly synthesized by polymerization of 3,3-bis(azidomethyl) oxetane (BAMO) and 3-azidomethyl-3-methyloxetane (AMMO) in a triisobutylaluminum–water catalytic system, and their physicochemical, physicomechanical, and themochemical properties were studied. It was found that with increasing fraction of poly-AMMO in the BAMO/AMMO copolymers the strength properties of the copolymers enhance and the degree of crystallinity decreases.

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I. Garaev

Kazan National Research Technical University

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Email: nppdiol@mail.ru
俄罗斯联邦, p/b 48, Kazan, Tatarstan, 420139

A. Kostochko

Kazan National Research Technical University

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俄罗斯联邦, p/b 48, Kazan, Tatarstan, 420139

A. Petrov

Kazan National Research Technical University

Email: nppdiol@mail.ru
俄罗斯联邦, p/b 48, Kazan, Tatarstan, 420139

E. Ibragimov

Research Institute of Polymer Materials

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俄罗斯联邦, ul. Chistopol’skaya 16, Perm, 614101

A. Golubev

Research Institute of Polymer Materials

Email: nppdiol@mail.ru
俄罗斯联邦, ul. Chistopol’skaya 16, Perm, 614101

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