电邮这篇文章 The First Heterometallic Acetate-Bridged Pt(II)–Pd(II) Complex: Synthesis, Structure, and Formation of Bimetallic PtPd2 Nanoparticles
- 作者: Cherkashina N.V.1, Churakov A.V.1, Yakushev I.A.1, Stolyarov I.P.1, Khrustalev V.N.2, Khramov E.V.2,3, Markov A.A.1, Smirnova N.S.1, Zubavichus Y.V.3, Dorovatovskii P.V.3, Dobrokhotova Z.V.1, Ilyukhin A.B.1, Vargaftik M.N.1
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Peoples’ Friendship University of Russia
- National Research Center Kurchatov Institute
- 期: 卷 45, 编号 4 (2019)
- 页面: 253-265
- 栏目: Article
- URL: https://bakhtiniada.ru/1070-3284/article/view/214683
- DOI: https://doi.org/10.1134/S107032841904002X
- ID: 214683
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详细
The reaction of platinum acetate blue, empirically described as Pt(OOCMe)2.50, with palladium(II) acetate Pd3(μ-OOCMe)6 gave the first heterometallic acetate-bridged platinum(II) and palladium(II) complex Pd2Pt(μ-OOCMe)6 (I) as co-crystallizates 17Pd2Pt(μ-OOCMe)6 ⋅ 4Pd3(μ-OOCMe)6 ⋅ 42C6H6 (IIa) and 17Pd2Pt(μ-OOCMe)6 ⋅ 4 Pd3(μ-OOCMe)6 (IIb). Single crystal X-ray diffraction (CIF files CCDC nos. 1568105 and 1852744), EXAFS, and quantum chemical studies (DFT and QTAIM) of complex I revealed a slightly distorted triangular structure similar to the structure of palladium(II) acetate Pd3(μ-OOCMe)6 and hypothetical platinum(II) complex Pt3(μ-OOCMe)6. The thermal decomposition of complex IIa gives the bimetallic alloy PtPd2. A combined X-ray diffraction and EXAFS study demonstrated that the obtained material consists of core (Pt)–shell (Pd) particles with an average size of ~28 nm and a minor amount of smaller (~5 nm) PdO nanoparticles on the surface. The obtained results are useful for the understanding of the nature and structure of the supported phase of heterogeneous Pt–Pd catalysts.
作者简介
N. Cherkashina
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
A. Churakov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
I. Yakushev
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
I. Stolyarov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
V. Khrustalev
Peoples’ Friendship University of Russia
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 117198
E. Khramov
Peoples’ Friendship University of Russia; National Research Center Kurchatov Institute
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 117198; Moscow, 123182
A. Markov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
N. Smirnova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
Ya. Zubavichus
National Research Center Kurchatov Institute
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 123182
P. Dorovatovskii
National Research Center Kurchatov Institute
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 123182
Zh. Dobrokhotova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
A. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
M. Vargaftik
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: wahr36@gmail.com
俄罗斯联邦, Moscow, 119991
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