Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability


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Mononuclear complexes (3-XPyH)[SbBr6] (X = Cl (I), Br (II)) are synthesized by the reactions of Sb2O3, Br2, and 3-XPy in HBr. Compound I is characterized by X-ray structure analysis (СIF file CCDC no. 1818602). The crystals of compounds I and II are isostructural. The thermal stability of the synthesized complexes is studied by thermogravimetry.

作者简介

S. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

编辑信件的主要联系方式.
Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090 ; Novosibirsk, 630090

M. Bondarenko

Novosibirsk State University

Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

P. Abramov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090 ; Novosibirsk, 630090

I. Korolkov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090 ; Novosibirsk, 630090

P. Plyusnin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090 ; Novosibirsk, 630090

M. N. Sokolov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Kazan (Volga Region) Federal University

Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090 ; Kazan

V. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: adonin@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090 ; Novosibirsk, 630090

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