p-Cymene Ruthenium Halide Complexes with a Heterocyclic Carbene


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The reaction of (p-cymene)Ru(Me2Im)Cl2 with excess Me2ImCO2 in acetonitrile in the presence of NH4PF6 afforded the amino complex [(p-cymene)Ru(Me2Im)(NH3)Cl]PF6. The reaction of (p‑cymene)Ru(Me2Im)Cl2 with excess anhydrous SnCl2 gave the complex (p-cy-mene)-Ru(Me2Im)Cl(SnCl3), whereas treatment of dimeric iodide complex [(p-cymene)RuI2]2 with Me2ImCO2 in acetonitrile gave the ionic compound [Me2ImH][(p-cymene)RuI3]. CIF files: CCDC nos. 1841649 (I), 1841650 (II), 1841648 (III).

作者简介

S. Shapovalov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: schss@yandex.ru
俄罗斯联邦, Moscow, 119991

O. Tikhonova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: schss@yandex.ru
俄罗斯联邦, Moscow, 119991

A. Pasynskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: schss@yandex.ru
俄罗斯联邦, Moscow, 119991

I. Skabitskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: schss@yandex.ru
俄罗斯联邦, Moscow, 119991

S. Sakharov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: schss@yandex.ru
俄罗斯联邦, Moscow, 119991

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