Enviar artigo por via de e-mail Magnetism and Structure of a 3D Uncommon Pentanuclearcopper(II) Coordination Polymer
- Autores: Jin J.C.1, Zhong H.R.2, Ma A.Q.2, Huang Y.J.2, Qiu S.W.3, Liu J.Q.2, Luo M.M.2, Xu J.W.2, Wang Y.Y.4, Sakiyama H.S.5
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Afiliações:
- Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University
- Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
- School of Inspection Science, Guangdong Medical University
- Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University
- Department of Science, Faculty of Science, Yamagata University,
- Edição: Volume 44, Nº 11 (2018)
- Páginas: 693-700
- Seção: Article
- URL: https://bakhtiniada.ru/1070-3284/article/view/214181
- DOI: https://doi.org/10.1134/S1070328418110039
- ID: 214181
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Resumo
A 3D coordination polymer, [Na3KCu5(Tar)2(HTar)2(H2O)7] (I) (H2Tar = tartaric acid), was synthesized by the reaction of potassium sodium tartrate and Cu(NO3)2 and characterized by X-ray single crystal diffraction (СIF file CCDC no. 1575976). Complex I is built up in a shell-like manner based on inner two symmetry-related pentanuclear copper cores, the cores are surrounded by coordinated synchronously Na and K atoms, which shapes into 3D nanoporous architecture. Additionally, I exhibits antiferromagnetic behavior.
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Sobre autores
J. Jin
Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University
Autor responsável pela correspondência
Email: jcjgd2017@126.com
República Popular da China, Anhui, 23701
H. Zhong
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
República Popular da China, Dongguan, 523808
A. Ma
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Autor responsável pela correspondência
Email: maqandght@126.com
República Popular da China, Dongguan, 523808
Y. Huang
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
República Popular da China, Dongguan, 523808
S. Qiu
School of Inspection Science, Guangdong Medical University
Email: wyaoyuxb@126.com
República Popular da China, Dongguan, 523808
J. Liu
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
República Popular da China, Dongguan, 523808
M. Luo
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
República Popular da China, Dongguan, 523808
J. Xu
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
República Popular da China, Dongguan, 523808
Y. Wang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University
Autor responsável pela correspondência
Email: wyaoyuxb@126.com
República Popular da China, Xi’an, 710069
H. Sakiyama
Department of Science, Faculty of Science, Yamagata University,
Email: wyaoyuxb@126.com
Japão, Kojirakawa, Yamagata 990-8560
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