电邮这篇文章 Synthesis and physicochemical studies of the compounds based on [Ni(Dien)(NH3)3]2+ and [Ni(Trien)(NH3)2]2+ cations and [Re6Se8(CN)4(OH)2]4– octahedral cluster anion
- 作者: Ermolaev A.V.1, Smolentsev A.I.1,2, Mironov Y.V.1,2
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- 期: 卷 42, 编号 11 (2016)
- 页面: 730-736
- 栏目: Article
- URL: https://bakhtiniada.ru/1070-3284/article/view/213345
- DOI: https://doi.org/10.1134/S1070328416110026
- ID: 213345
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详细
Two new compounds, [Ni(Dien)(NH3)3]2[Re6Se8(CN)4(OH)2] • 5.5H2O (I) and [Ni(Trien)(NH3)2]2[Re6Se8(CN)4(OH)2] • 4.67H2O (II) (Dien is diethylenetriamine and Trien is triethylenetetraamine), are synthesized by layering solutions of NiCl2 • 6H2O in aqueous ammonia with the addition of the corresponding amines onto an aqueous solution of cluster salt Cs2.75K1.25[Re6Se8(CN)4(OH)2] • H2O. The structures of both complexes are determined by single-crystal X-ray diffraction analysis (CIF files CCDC 1446999 (I) and 1447000 (II)). The compounds are characterized by IR spectroscopy and elemental and thermogravimetric analyses.
作者简介
A. Ermolaev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: yuri@niic.nsc.ru
俄罗斯联邦, pr. akademika Lavrent’eva 3, Novosibirsk, 630090
A. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: yuri@niic.nsc.ru
俄罗斯联邦, pr. akademika Lavrent’eva 3, Novosibirsk, 630090; Novosibirsk
Yu. Mironov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
编辑信件的主要联系方式.
Email: yuri@niic.nsc.ru
俄罗斯联邦, pr. akademika Lavrent’eva 3, Novosibirsk, 630090; Novosibirsk
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