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Vol 55, No 2 (2019)

Article

Electrodeposition of Nanocrystalline Fe—W Coatings from a Citrate Bath

Belevskii S.S., Gotelyak A.V., Yushchenko S.P., Dikusar A.I.

Abstract

The electrode processes occurring during electrodeposition of nanocrystalline Fe-W alloy coatings from a citrate bath containing iron(II) sulfate and a tungstate (pH 6.9; 80°C, graphite anode) are studied by cyclic voltammetry. The current efficiency of alloy electrodeposition is up to 30%, if the applied current density is confined to the range of 2–5 A/dm2. The limitation on range of applied current densities is twofold: the lower limit is dictated by the diffusion-limited current density due to the reduction of the oxidized form of iron-citrate complex that forms at the bath preparation stage as a result of oxidation of Fe(II) species in a citrate solution; while the upper limit is imposed by the occurrence of side reactions such as the hydrogen evolution reaction and/or reduction of organic components of the bath. The use of an iron anode seems to be promising in this deposition process (the current efficiency of anodic dissolution of Fe in this bath is 93 ± 2%). The deposited coatings contain ~25 at % tungsten and their microhardness (which can be up to 900 kgF/mm2) depends on the volume current density. The studied system holds promise for application in mask-free localized electrodeposition.

Surface Engineering and Applied Electrochemistry. 2019;55(2):119-129
pages 119-129 views

Fabrication of Fe–Al2O3 Composite Layer on the Surface of Carbon Steel via Gas Tungsten Arc Cladding

Shajari Y., Bahmani E., Lori Amini A., Seyedraoufi Z.S., Razavi S.H., Rabieifar A.

Abstract

In this study, Fe–Al2O3 composite cladding is fabricated on the carbon steel AISI 1040 (CK40) substrates by the cost-effective process of gas tungsten arc welding. For this purpose, after milling, Fe–Al2O3 composite powders were placed on the steel surface through the sodium silicate binder. After the surface was dried, under a constant voltage and current in a range of 110 to 180 A, the melting and the fabrication of the surface composite were carried out. For non-destructive investigations, samples were analyzed by radiographic testing which showed that there are no cracks in the surface layer created and Al2O3 particles are distributed uniformly in the surface layer. Microstructural examinations by optical microscopy, scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction proved the presence of a pure Fe–Al2O3 phase in the surface layer. Microscopic images showed coaxial fine grains in the weld metal, which can be caused by a thermal gradient between the weld metal and substrates and rapid solidification. Increasing the current due to enhanced input heat leads to a reduction of the grain size and an increase of dramatic micro hardness that leads to agglomeration of Al2O3 particles and reduction of the quality of the cladding layer. The purpose of this research is to achieve optimal parameters of claddings to attain specific objectives of engineering by using steel via an inexpensive supplementary method.

Surface Engineering and Applied Electrochemistry. 2019;55(2):130-137
pages 130-137 views

Electrodeposition of Ni–TiO2 Composite Coatings Using Electrolyte Based on a Deep Eutectic Solvent

Danilov F.I., Kityk A.A., Shaiderov D.A., Bogdanov D.A., Korniy S.A., Protsenko V.S.

Abstract

Deep eutectic solvents are nowadays considered to be very promising analogues of room temperature ionic liquids. They can make a significant contribution to the development of novel efficient, economic and environmentally friendly processes, particularly, in surface engineering and electroplating. The electrodeposition of Ni–TiO2 composite coatings from an electrolyte based on a deep eutectic solvent, ethaline, was studied in this work. Titania particles were introduced into the plating bath in the form of Degussa P 25 nanopowder. The content of titania in electrodeposited composite coatings was shown to depend on the stirring rate, current density and TiO2 concentration in the electrolyte and can reach ca. 2.35 wt %. The microstructure and the surface morphology of the obtained composite layers were characterized. The formation of nanocrystalline nickel matrix was detected. The introduction of TiO2 particles into nickel-based coatings resulted in an increase in the microhardness of deposits. The data obtained via the electrochemical impedance spectra technique revealed an improvement in the corrosion resistance of coatings due to titania particles incorporation into deposits. The Ni–TiO2 composite coatings manifested a photocatalytic activity towards the reaction of photochemical degradation of methylene blue organic dye in water solution.

Surface Engineering and Applied Electrochemistry. 2019;55(2):138-149
pages 138-149 views

Photosensitivity Selectivity of Cadmium Sulfide Films during Electrochemical Growth

Demidenko I.V., Ishimov V.M., Mangir A.G.

Abstract

The results of observations of the photosensitivity of CdS films during their electrochemical deposition are described. An equivalent electrical circuit characterizing the electrode processes is proposed. A mathematical model to describe these processes is constructed.

Surface Engineering and Applied Electrochemistry. 2019;55(2):150-156
pages 150-156 views

Microstructural Effects on the Surface of Materials in Magnetic Fields

Anisovich A.G.

Abstract

Changes in metallic and nonmetallic materials under the influence of a pulsed magnetic field are studied, using the method of target metallography. It is shown that the structural changes are at the minimum detectable level of the microscopic method with peak gains. It is established that local variation in structure and degradation in the sharpness of separate surface areas of the samples independent of errors in focusing is a general structure change in the action of a magnetic field. The stresses of the third kind are considered to be possible reasons for the change in structure.

Surface Engineering and Applied Electrochemistry. 2019;55(2):157-161
pages 157-161 views

Mechanism of Formation of Plane Surfaces with an Electric Arc

Bokov V.M., Sisa O.F., Mirzak V.Y.

Abstract

A new method is presented for two similar plane surfaces of high-performance dimensional treatment with an electric arc (DTEA) where the components are hard-to-cut materials in a bipolar mode without the traditional application of an electrode tool. In comparison to DTEA with the use of an electrode tool, this new method provides an increase in the efficiency of treatment by 230%. It is shown that for passing from unipolar DTEA of VK-15 hard alloy with a graphite electrode-tool to bipolar DTEA of two samples of the same alloy, a considerable increase in heat energy of the cathode area is found due to the energy of the arc column, which can overrun the heat energy of the anode area and lead to inversion, that is, a change in the direction of the prevailing electric erosion. This increase in the heat energy of the arc cathode area explains the growth in the productivity of the bipolar DTEA of two samples of the hard alloy VK-15 over the unipolar one.

Surface Engineering and Applied Electrochemistry. 2019;55(2):162-171
pages 162-171 views

Corrosion Inhibition of Two Aluminum Silicon Alloys in 0.5 M HCl Solution by Some Azole Derivatives Using Electrochemical Techniques

Abdallah M., Fouda A.S., El-Nagar D.A., Alfakeer M., Ghoneiim M.M.

Abstract

The inhibiting action of three derivatives of azole compounds has been investigated for the corrosion of two aluminum-silicon alloys in 0.5 M HCl solution using some electrochemical measurements such as potentiodynamic polarization, electrochemical impedance, and electrochemical frequency modulation. The morphology of the surface was examined by the scanning electron microscopy. It was found that the inhibition efficiency increases with the increase in the concentration of azole compounds. Those compounds acted as mixed inhibitors and their inhibiting effect was revealed through the formation of an adsorbed film, which blocked the active site present on the alloys. The adsorption process follows the Freundlich isotherm. The addition of Si to Al electrode increases in the corrosion protection of the alloys in the following sequence: Alloy II > Alloy I. The inhibition efficiencies obtained via different techniques are consistent with each other.

Surface Engineering and Applied Electrochemistry. 2019;55(2):172-182
pages 172-182 views

Tribological Characterization of the Modified Cast Al–Si Eutectic Alloys

Bidmeshki C., Shajari Y., Abouei V.

Abstract

The focus of this investigation is on the modification of Fe-rich intermetallics morphology and wear and friction properties of eutectic Al–Si alloys. Eutectic Al–Si specimens were fabricated by tilt casting after addition of different amounts of iron and manganese to the molten alloy. Dry sliding tribological behavior of the samples was investigated using a reciprocating wear tester at room temperature in atmospheric environment. It is found that the addition of iron up to 1.5 wt % to the alloy decreases the wear resistance of the alloy owing to the formation of brittle plate-like interme-tallic compounds of β-Al5FeSi. As Manganese is added to the β-containing alloy up to the half of the iron content (corresponding to a Mn/Fe ratio of 0.5), the platelet phases are completely replaced by the star-like intermetallic α-Al15(Fe, Mn)3Si2 resulting in improved wear resistance of the alloy. Introducing 0.8 wt.pct Mn to the alloy containing 1.6 wt % Fe did not convert the plate-like beta intermetallics to the modified alpha compounds completely and had no impressive impact on the wear rate of the alloy.

Surface Engineering and Applied Electrochemistry. 2019;55(2):183-190
pages 183-190 views

Analysis of Gaseous Products of Plasma Electrolytic Oxidation of Aluminum

Golovenko V.A., Kalinichenko O.A., Roenko E.V., Gurevina N.L., Snezhko L.A.

Abstract

The measurements of the volume and density of the anodic gas evolved in anodic-spark oxidation showed that the ratio of hydrogen to oxygen is about 1.6–1.8 at current densities of 1000–3000 A m−2. The fraction of anodic hydrogen is in the range of 1.17–1.38% among the total hydrogen released during the anodic-spark oxidation from both electrodes. Hypothetical reactions responsible for the appearance of hydrogen in the anodic gas are considered. It is shown that the oxide current output calculated in accordance with electrochemical regularities decreases with increasing current density, in the range of 11–18%. This is indicative of the enhancing role of thermochemical processes upon a higher intensity of sparks and an increase in their sizes.

Surface Engineering and Applied Electrochemistry. 2019;55(2):191-196
pages 191-196 views

Electrical Processing of Whey. Role of Construction, Technological and Energy Characteristics of Reactors

Vrabie E.G., Bologa M.K., Paladii I.V., Stepurina T.G., Vrabie V.G., Goncharuk V.P., Polikarpov A.A., Sprinchan C.G.

Abstract

The purpose of this work was to study the basic construction, energy, and technological features of the electrochemical reactors used in the manufacture of whey, a dairy by-product and a biologically very valuable liquid. The choice of optimal regimes for processing various types of whey was specified aimed at increasing the efficiency of the recovery of whey protein fractions in the protein-mineral concentrates through reduction of the energy consumption. It is demonstrated that features of the electric reactors must be reasonably selected, including the distances between the electrodes and between the electrodes and the membrane, as well as their geometric shape, to avoid occurrence of dead areas and to ensure a high efficiency of the process. It was also important to find the most appropriate options for electric parameters and processing regimes (periodic or continuous). In addition, the ratio of the whey volume and the main electrode area, the type of the regimes membrane, the initial content of the dry matter in each type of the whey (in particular, its protein composition), and the compositions and concentration of the anodic (secondary) liquid, were taken into account. The results of the study are significant for the development of a wasteless technology of processing the dairy by-products.

Surface Engineering and Applied Electrochemistry. 2019;55(2):197-209
pages 197-209 views

Removal of Copper from Aqueous Solution Using Electrocoagulation: Importance of Stirring Effect

Kessentini I., Mousser H., Zouari S., Bargui M.

Abstract

Electrocoagulation with aluminum and stainless steel electrodes was investigated. Electrocoagulation tests were performed to treat synthetic wastewater containing heavy metallic ions (Cu2+), with concentrations ranging from 100 to 600 ppm. Concentrations of the remaining copper and coagulant (Al3+), generated by electrochemical oxidation of the anode, were optimized by an experimental design methodology. The study was conducted using a Doehlert matrix. The factors considered are: the initial concentration of copper (CCu0); the stirring speed (N); the current density (J); and the electrolysis time (t). As for the response functions measured by atomic absorption, they imply the final concentration of the metallic ions of copper (Y1) and of the metallic ions of aluminum accumulated in the wastewater after electrocoagulation treatment (Y2). The isoresponse curves and the optimum path study of the two retained responses showed that the two optima were found to be opposite. In order to minimize the two responses and determine the conditions of electrocoagulation that satisfy the requirements of the Tunisian standard for effluent discharges NT-106-02 (≤1 ppm for copper and ≤ 10 ppm for aluminum), multicriteria optimization using the desirability function was achieved. In so doing, the determined optimal operating conditions for the process of electrocoagulation were: CCu0 = 421.43 ppm, N = 44.19 rpm, J = 656.41 mA dm−2 and t = 65.12 min, while the corresponding estimated response values were 0.25 ppm and 3.38 ppm for cooper and coagulant (Al3+), respectively. The removal efficiency over 98% was reached for copper. In addition, the results of the study demonstrate that a simultaneous increase of the current density and the stirring speed notably reduces not only the concentration of the remaining copper but also the treatment duration, without inducing a strong increase of the sludge.

Surface Engineering and Applied Electrochemistry. 2019;55(2):210-218
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Analysis of Variation in Circuit Parameters for Substitution of Weed Plant Tissue under Electric Impulse Action

Yudaev I.V.

Abstract

To substantiate the quantitative values of the process of destruction of weeds by means of electric impulse and to elucidate the mechanism of damage and the sequence of disturbances that occur in the internal structure of the processed plants, it is necessary to know not only the design of the electrical circuit of the plant tissue substitution but also to have information on the nature of the change in the parameters of the elements of this scheme during electric damage. The presented technique allows (with the help of inexpensive and accessible technical means) to control the damage to the tissues of a weed plant and to calculate quantitative values using developed mathematical apparatus. The analysis shows that the damage to weed plant tissues can be characterized, first of all, by the loss of cell membranes in their semipermeable functions and an increase in the active conductivity of the processed areas of plants. Such changes in the internal structure of plant tissue lead to loss of cell viability in the areas subjected to the electric impulse treatment. The presented analysis fits the current thinking of biophysicists on the electrical damage to the internal structure of biological objects. The technological studies of the process of the electric impulse irreversible damage to plant tissues conducted, based on the analysis presented in the article, allow us to limit the supplied electric energy that makes it possible to make electric impulse weeding an energy-saving means of combating weeds.

Surface Engineering and Applied Electrochemistry. 2019;55(2):219-224
pages 219-224 views

Characterization of Interdigital Electrode Sensors

Cojocaru V.P.

Abstract

The paper aims to determine the influence of the chosen geometrical parameters of an interdigital sensor and of the measuring cell on the sensor performance, with the final goal of optimizing those parameters. The cell here is a capacitive cell or resistive cell for titration without a particular type. The AC/DC analysis has been carried out and the results are presented as graphs and figures. In modelling, COMSOL Multiphysics software was used.

Surface Engineering and Applied Electrochemistry. 2019;55(2):225-231
pages 225-231 views

Peculiarities of Control over Electron-Beam Additive Form Manufacturing

Shcherbakov A.V., Rodyakina R.V., Kozhechenko A.S., Vakhmyanin N.M., Gaponova D.A., Rubtsov V.P.

Abstract

This work analyzes the manufacturing process of an electron-beam additive form by heating as a result of remelting the supplied filler wire as a control object. Control actions and output values are designated that can be used in constructing a control systems with feedback. A mathematical modeling technique is used to study heat transfer in a nonstationary formulation, taking into account the influence of the latent heat of fusion. The transient processes of temperature changes were studied at points, whose values can be used to estimate the extension of the weld pool and the degree of metal overheating. An analysis of the results of computational experiments is carried out, and the range of variations of control actions are shown. The possibility of an independent temperature control in the range of the beam and the extension of the liquid bath is also justified. Recommendations are given for the technical implementation of the system and the option of implementing local regulators, types of sensors, and their installation.

Surface Engineering and Applied Electrochemistry. 2019;55(2):232-240
pages 232-240 views