Study of the reactivity of organonickel sigma-complexes towards nitriles

Z. N. Gafurov; I. F. Sakhapov; V. M. Babaev; A. B. Dobrynin; V. A. Kurmaz; K. E. Metlushka; I. Kh. Rizvanov; G. R. Shaikhutdinova; O. G. Sinyashin; D. G. Yakhvarov

doi:10.1007/s11172-017-1725-8

Study of the reactivity of organonickel sigma-complexes towards nitriles

作者: Gafurov Z.N.¹^,2, Sakhapov I.F.¹^,2, Babaev V.M.¹, Dobrynin A.B.¹, Kurmaz V.A.³, Metlushka K.E.¹, Rizvanov I.K.¹, Shaikhutdinova G.R.¹, Sinyashin O.G.¹, Yakhvarov D.G.¹^,2
隶属关系:
1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences
2. A. M. Butlerov Institute of Chemistry, Kazan Federal University
3. Institute of Problems of Chemical Physics, Russian Academy of Sciences
期: 卷 66, 编号 2 (2017)
页面: 254-259
栏目: Full Articles
URL: https://bakhtiniada.ru/1066-5285/article/view/239977
DOI: https://doi.org/10.1007/s11172-017-1725-8
ID: 239977

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详细

The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2´-bipyridine, towards nitriles (acetonitrile, propionitrile, chloroacetonitrile, benzonitrile) has been investigated. This reaction leads to imines by formation of new carbon—carbon bond between aromatic fragment and nitrile group C≡N.

作者简介

Z. Gafurov

A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University

Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008

I. Sakhapov

A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences; A. M. Butlerov Institute of Chemistry, Kazan Federal University

Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008