Отправить статью по E-mail Crystal structure and two-level supramolecular organization of glycinium triiodide
- Авторы: Shestimerova T.A.1, Bykov M.A.1, Wei Z.2, Dikarev E.V.2, Shevelkov A.V.1
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Учреждения:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Department of Chemistry, University at Albany
- Выпуск: Том 68, № 8 (2019)
- Страницы: 1520-1524
- Раздел: Full Article
- URL: https://bakhtiniada.ru/1066-5285/article/view/243447
- DOI: https://doi.org/10.1007/s11172-019-2586-0
- ID: 243447
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Аннотация
Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)2(I3)2via (N)H···O, (N)H···I, and (O)H···I hydrogen bonds. The dimers are further linked into chains by secondary I···I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.
Об авторах
T. Shestimerova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
Россия, Build. 3, 1 Leninskie Gory, Moscow, 119991
M. Bykov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
Россия, Build. 3, 1 Leninskie Gory, Moscow, 119991
Z. Wei
Department of Chemistry, University at Albany
Email: shev@inorg.chem.msu.ru
США, Albany, New York, 12222
E. Dikarev
Department of Chemistry, University at Albany
Автор, ответственный за переписку.
Email: edikarev@albany.edu
США, Albany, New York, 12222
A. Shevelkov
Department of Chemistry, M. V. Lomonosov Moscow State University
Автор, ответственный за переписку.
Email: shev@inorg.chem.msu.ru
Россия, Build. 3, 1 Leninskie Gory, Moscow, 119991
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