Crystal structure and two-level supramolecular organization of glycinium triiodide
- 作者: Shestimerova T.A.1, Bykov M.A.1, Wei Z.2, Dikarev E.V.2, Shevelkov A.V.1
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隶属关系:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Department of Chemistry, University at Albany
- 期: 卷 68, 编号 8 (2019)
- 页面: 1520-1524
- 栏目: Full Article
- URL: https://bakhtiniada.ru/1066-5285/article/view/243447
- DOI: https://doi.org/10.1007/s11172-019-2586-0
- ID: 243447
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详细
Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)2(I3)2via (N)H···O, (N)H···I, and (O)H···I hydrogen bonds. The dimers are further linked into chains by secondary I···I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.
作者简介
T. Shestimerova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
M. Bykov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
Z. Wei
Department of Chemistry, University at Albany
Email: shev@inorg.chem.msu.ru
美国, Albany, New York, 12222
E. Dikarev
Department of Chemistry, University at Albany
编辑信件的主要联系方式.
Email: edikarev@albany.edu
美国, Albany, New York, 12222
A. Shevelkov
Department of Chemistry, M. V. Lomonosov Moscow State University
编辑信件的主要联系方式.
Email: shev@inorg.chem.msu.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
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