Email this article Quantum-chemical modeling of possible reactions of Roussin’s red esters with aryl ligands in DMSO solution
- Authors: Emel’yanova N.S.1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Issue: Vol 67, No 8 (2018)
- Pages: 1330-1334
- Section: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/242775
- DOI: https://doi.org/10.1007/s11172-018-2221-5
- ID: 242775
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Abstract
Possible reactions of Roussin’s red esters [Fe2(μ-SC6H4R)2(NO)4], where R = H, o-NH2, m-NO2, m-OH, or m-NH2, in DMSO solution were investigated by quantum chemical modeling. It was shown that in these systems, numerous reactions can occur, including NO donation, ligand substitution, and decomposition into mononuclear iron nitrosyl complexes. The resulting compounds are also NO donors.
About the authors
N. S. Emel’yanova
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: n_emel@mail.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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