Enviar artigo por via de e-mail Reaction of ferrocenium ion with secondary phosphines: replacement of cyclopentadienyl ligand rather than its C—H functionalization
- Autores: Chamkin A.A.1, Krivykh V.V.1, Shtel′tser N.A.1, Utegenov K.I.1, Dolgushin F.M.1, Ustynyuk N.A.1
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Afiliações:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Edição: Volume 68, Nº 7 (2019)
- Páginas: 1380-1383
- Seção: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/243426
- DOI: https://doi.org/10.1007/s11172-019-2565-5
- ID: 243426
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Resumo
The reactions of ferrocenium salts with secondary phosphines Ph2PH, Cy2PH, and Et2PH proceed as replacement of the cyclopentadienyl ring to afford half-sandwich complexes [C5H5Fe(R2PH)3](X) (X = PF6, BF4) rather than ferrocenylphosphonium salts [C5H5FeC5H4— (PHR2)](X).
Sobre autores
A. Chamkin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ustynyuk@ineos.ac.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
V. Krivykh
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ustynyuk@ineos.ac.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
N. Shtel′tser
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ustynyuk@ineos.ac.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
K. Utegenov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ustynyuk@ineos.ac.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
F. Dolgushin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ustynyuk@ineos.ac.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
N. Ustynyuk
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Autor responsável pela correspondência
Email: ustynyuk@ineos.ac.ru
Rússia, 28 ul. Vavilova, Moscow, 119991
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