Enviar artigo por via de e-mail Photonics of tetramethoxy-1,4-distyrylbenzene
- Autores: Atabekyan L.S.1, Avakyan V.G.1,2, Nuriev V.N.1,3, Vatsadze S.Z.1,3, Gromov S.P.1,3
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Afiliações:
- Photochemistry Center, Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Edição: Volume 67, Nº 11 (2018)
- Páginas: 2016-2024
- Seção: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/243163
- DOI: https://doi.org/10.1007/s11172-018-2323-0
- ID: 243163
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Resumo
Photonics of tetramethoxy-1,4-distyrylbenzene in MeCN was studied by absorption, luminescence, and laser kinetic spectroscopies. Photoinduced transformations of the compound in question involve cis–trans-isomerization, intersystem crossing, fast and delayed fluorescence, and electron transfer. The ground-state structure and vibrational spectrum, as well as the energies and structures of excited singlet and triplet states were calculated by the DFT/PBE and TDDFT/PBE0 methods. The assignment of vibronic bands in the absorption spectra was made and the energies of corresponding transitions were calculated.
Sobre autores
L. Atabekyan
Photochemistry Center, Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences
Autor responsável pela correspondência
Email: levat51@mail.ru
Rússia, 7a ul. Novatorov, Moscow, 119421
V. Avakyan
Photochemistry Center, Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences; Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: levat51@mail.ru
Rússia, 7a ul. Novatorov, Moscow, 119421; 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
V. Nuriev
Photochemistry Center, Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University
Email: levat51@mail.ru
Rússia, 7a ul. Novatorov, Moscow, 119421; Build. 3, 1 Leninskie Gory, Moscow, 119991
S. Vatsadze
Photochemistry Center, Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University
Email: levat51@mail.ru
Rússia, 7a ul. Novatorov, Moscow, 119421; Build. 3, 1 Leninskie Gory, Moscow, 119991
S. Gromov
Photochemistry Center, Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University
Email: levat51@mail.ru
Rússia, 7a ul. Novatorov, Moscow, 119421; Build. 3, 1 Leninskie Gory, Moscow, 119991
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