Experimental determination of the standard enthalpy of formation of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine and evaluation of its performance as a dispersant of solid fuels


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The energy of combustion ΔH°c of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine (BFP) was measured by calorimetry in the oxygen atmosphere and the standard enthalpy of formation ΔH°f was calculated. The real ΔH°f value was found to be 33 kJ mol−1 higher than reported before. The obtained results were used for correction of the evaluated efficiency of using BFP as a solid fuel dispersant for rocket ramjet engines, which showed high BFP performance.

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D. Lempert

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: lempertdavid@yandex.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

A. Kazakov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempertdavid@yandex.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

A. Sheremetev

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: lempertdavid@yandex.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

A. Gladyshkin

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: lempertdavid@yandex.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

A. Nabatova

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempertdavid@yandex.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432

L. Yanovskii

Institute of Problems of Chemical Physics, Russian Academy of Sciences; Department of Chemistry, M. V. Lomonosov Moscow State University

Email: lempertdavid@yandex.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432; Build. 3, 1 Leninskie Gory, Moscow, 119991

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