Email this article Supramolecular structuring of aqueous solutions of strong acids: manifestations in light scattering, NMR, and oxidation kinetics. Does liquid have a drop-like nature?
- Authors: Lagodzinskaya G.V.1, Laptinskaya T.V.2, Kazakov A.I.1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Department of Physics, M. V. Lomonosov Moscow State University
- Issue: Vol 67, No 12 (2018)
- Pages: 2212-2223
- Section: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/243219
- DOI: https://doi.org/10.1007/s11172-018-2358-2
- ID: 243219
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Abstract
The properties of large (~100 nm) aggregates, that is, solvate associates formed in aqueous solutions of perchloric acid, including their stability in time, dependence of their structure on the solution composition and preparation procedure, and effects of temperature and mechanical impacts were studied by light scattering methods. The slow supramolecular structuring in aqueous solutions of perchloric acid was compared with the previously studied structuring in aqueous solutions of nitric acid. A number of regularities and features that can significantly affect the chemical processes in these solutions were revealed.
About the authors
G. V. Lagodzinskaya
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: lago@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
T. V. Laptinskaya
Department of Physics, M. V. Lomonosov Moscow State University
Email: lago@icp.ac.ru
Russian Federation, Build. 2, 1 Leninskie Gory, Moscow, 119991
A. I. Kazakov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: lago@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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