Отправить статью по E-mail Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
- Авторы: Rozentsvet V.A.1, Kozlov V.G.1, Sablina N.A.1, Stotskaya O.A.1
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Учреждения:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- Выпуск: Том 67, № 8 (2018)
- Страницы: 1419-1425
- Раздел: Article
- URL: https://bakhtiniada.ru/1066-5285/article/view/242809
- DOI: https://doi.org/10.1007/s11172-018-2234-0
- ID: 242809
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Аннотация
Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta diene is characterized by predominantly 1,4-trans-structure and reduced unsaturation. The macromolecules of the cationic polybutadiene contain the initial tert-butyl and end chlorine-containing units.
Об авторах
V. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: rozentsvet@mail.ru
Россия, 10 ul. Komzina, Tol’yatti, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Россия, 10 ul. Komzina, Tol’yatti, 445003
N. Sablina
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Россия, 10 ul. Komzina, Tol’yatti, 445003
O. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Россия, 10 ul. Komzina, Tol’yatti, 445003
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