Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect


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The review addresses the special case of mechanical activation of solid-state chemical reactions when the stress field, strain, and defects in crystals are induced by the chemical reaction itself rather than by the external mechanical impact (chemo-mechanochemical (CMC) effect). This review presents the analysis and state-of-the-art of research activities in this area. Different cases of the CMC effect in homogeneous and heterogeneous systems are considered: with or without changes in the chemical composition, with or without formation of solid products, etc.

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V. Boldyrev

Institute of Solid-State Chemistry and Mechanochemistry, Siberian Branch of Russian Academy of Sciences; Novosibirsk State University

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Email: boldyrev@solid.nsc.ru
俄罗斯联邦, 18 ul. Kutateladze, Novosibirsk, 630128; 90 ul. Pirogova, Novosibirsk, 630090

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