Reaction of (chloromethyl)trichlorosilane with 2,2-dimethylpropane-1,3-diol


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(Chloromethyl)trichlorosilane reacts with 2,2-dimethylpropane-1,3-diol to produce α-carbofunctional heterocycles, 2-chloro-2-(chloromethyl)-5,5-dimethyl-1,3,2-dioxasilinane and 2,8-dichloro-2,8-bis(chloromethyl)-5,5,11,11-tetramethyl-1,3,7,9-tetraoxa-2,8-disilacyclododecane. The synthesized macroheterocycle is the first structurally characterized 1,3,7,9-tetraoxa-2,8-disilacyclododecane derivative.

Sobre autores

N. Lazareva

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: nataly_lazareva@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

I. Sterkhova

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: nataly_lazareva@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

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