Email this article Synthesis and structure of the first representative of pentacoordinate C,O-chelates with a dipeptide fragment, the fluorosilane Ts—Gly—(S)-Pro—N(Me)CH2SiMe2F
- Authors: Nikolin A.A.1, Kramarova E.P.1, Korlyukov A.A.1,2, Arkhipov D.E.1,2, Shipov A.G.1, Baukov Y.I.1, Lagunin A.A.1, Shmigol T.A.1, Negrebetsky V.V.1
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Affiliations:
- N. I. Pirogov Russian National Research Medical University
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 66, No 3 (2017)
- Pages: 571-573
- Section: Brief Communications
- URL: https://bakhtiniada.ru/1066-5285/article/view/240334
- DOI: https://doi.org/10.1007/s11172-017-1774-z
- ID: 240334
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Abstract
A reaction of bicyclic 2-sila-5-piperazinone, 2,2,4-trimethyl-1,4-diaza-2-silabicyclo-[4.3.0]nonan-5-one containing a proline moiety, and N-tosylglycine acyl chloride with subsequent hydrolysis of the primary unstable product to the intermediate disiloxane and its treatment with BF3•OEt2 furnished a first representative of pentacoordinate C,O-chelate halosilanes with a dipeptide fragment, namely, Ts—Gly—(S)-Pro—N(Me)CH2SiMe2F.
About the authors
A. A. Nikolin
N. I. Pirogov Russian National Research Medical University
Author for correspondence.
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
E. P. Kramarova
N. I. Pirogov Russian National Research Medical University
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
A. A. Korlyukov
N. I. Pirogov Russian National Research Medical University; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869; 28 ul. Vavilova, Moscow, 119991
D. E. Arkhipov
N. I. Pirogov Russian National Research Medical University; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869; 28 ul. Vavilova, Moscow, 119991
A. G. Shipov
N. I. Pirogov Russian National Research Medical University
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
Yu. I. Baukov
N. I. Pirogov Russian National Research Medical University
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
A. A. Lagunin
N. I. Pirogov Russian National Research Medical University
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
T. A. Shmigol
N. I. Pirogov Russian National Research Medical University
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
Vad. V. Negrebetsky
N. I. Pirogov Russian National Research Medical University
Email: nikolin_aa@rsmu.ru
Russian Federation, 1 ul. Ostrovityanova, Moscow, 117869
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