Determining the Parameters of the Ground Vibrational State of the 28SiH4 Molecule


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Abstract

For high-precision determination of the rotational-vibrational energies of the ground vibrational state of the SiH4 molecule, high-resolution rotational-vibrational spectrum of this molecule in the range 600–1200 cm–1 in which bands of the ν2/ ν4 dyad are located is analyzed. As a result, rotational and centrifugal distortion parameters of the ground vibrational state with a root-mean-square deviation of 2·10–4 cm–1 are obtained.

About the authors

N. I. Raspopova

Institute of Physics and Technology of National Research Tomsk Polytechnic University

Author for correspondence.
Email: raspopovani@tpu.ru
Russian Federation, Tomsk

O. V. Gromova

Institute of Physics and Technology of National Research Tomsk Polytechnic University

Email: raspopovani@tpu.ru
Russian Federation, Tomsk

E. S. Bekhtereva

Institute of Physics and Technology of National Research Tomsk Polytechnic University

Email: raspopovani@tpu.ru
Russian Federation, Tomsk

Z. Bauerecker

Technische Universität Braunschweig

Email: raspopovani@tpu.ru
Germany, Braunschweig

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