Isotope Substitution Effect in Polyatomic Molecules on the Example of 13C2H412C2H4 Substitution


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Аннотация

General points of the theory of isotope substitution are applied to an analysis of the isotope substitution effect for the substitution 13C2H412C2H4 in the ethylene molecule. On the basis of the isotope relations so obtained, numerical predictions of band centers and the most significant rotational, centrifugal, and resonance parameters are made here for the first time for the four lower vibrational states of the 13C2H4 molecule, which can be used to analyze the complicated vibrational-rotational structure of the above-mentioned vibrational states.

Авторлар туралы

E. Bekhtereva

Institute of Physics and Technology of the National Research Tomsk Polytechnic University; National Research Tomsk State University

Хат алмасуға жауапты Автор.
Email: lane_bes@mail.ru
Ресей, Tomsk; Tomsk

O. Gromova

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Email: lane_bes@mail.ru
Ресей, Tomsk

K. Berezkin

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Email: lane_bes@mail.ru
Ресей, Tomsk

N. Kashirina

Institute of Physics and Technology of the National Research Tomsk Polytechnic University

Email: lane_bes@mail.ru
Ресей, Tomsk

I. Konov

National Research Tomsk State University

Email: lane_bes@mail.ru
Ресей, Tomsk

S. Bauerecker

Institute of Theoretical and Physical Chemistry, Braunschweig University of Technology

Email: lane_bes@mail.ru
Германия, Braunschweig

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