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Coulomb Electron Interaction between an Adsorbate and Substrate: a Model of a Surface Dimer


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Abstract

The Coulomb interaction in the adsorption (adsorbate—substrate) system is reduced to a short-range repulsion between electrons of the adsorbed particle and atom of the substrate, which form a surface dimer. It is shown that allowance for this interaction leads to increased charge transfer between components of the dimer and decreased charge transfer between the dimer and metal substrate, which is caused by variation of the Fermi level in the adsorption system.

About the authors

S. Yu. Davydov

Ioffe Physical Technical Institute, Russian Academy of Sciences

Author for correspondence.
Email: Sergei_Davydov@mail.ru
Russian Federation, St. Petersburg, 194021

A. V. Zubov

St. Petersburg National Research University of Information Technologies, Mechanics, and Optics (ITMO University)

Email: Sergei_Davydov@mail.ru
Russian Federation, St. Petersburg, 197101

A. A. Lebedev

Ioffe Physical Technical Institute, Russian Academy of Sciences

Email: Sergei_Davydov@mail.ru
Russian Federation, St. Petersburg, 194021

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