Influence of ion energies on the structure, composition, and properties of multilayer Ti–Al–Si–N ion-plasma-deposited coatings

Abstract

It is established that the energy of deposited particles influences the structure, composition, and properties of multilayer nitride coatings consisting of alternating layers of nanocrystalline TiN and amorphous Si₃N₄ phases with inclusions of nanocrystalline hexagonal AlN formed at energies of titanium, aluminum, and silicon ions exceeding ~317 × 10^–19, 267 × 10^–19, and 230 × 10^–19 J, respectively. As the energy of titanium ions bombarding the substrate increases above ~512 × 10^–19 J, the phase transition from disordered TiN_x to Ti₃N₂ and the appearance of 2- to 3-nm-thick sublayers in 15-nm-thick nanocrystalline TiN_x layers take place in the coating. The maximum hardness of such coatings reaches a level of ~54 GPa.