Deposition of nanocrystalline nonstoichiometric chromium oxide coatings on the surface of multiwalled carbon nanotubes by chromium acetylacetonate vapor pyrolysis

Abstract

Nanocrystalline coatings of nonstoichiometric chromium oxide have been obtained for the first time on the surface of multiwalled carbon nanotubes (MWCNTs) by the method of metalorganic chemical-vapor deposition using chromium acetylacetonate as a precursor. The new hybrid nanomaterial (Cr₂O_2.4/MWCNT) has been characterized by X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. It is established that oxidation of the hybrid nanomaterial in air under soft conditions (at 380°C) leads to the formation of nanocrystalline chromium oxide (Cr₂O₃) on the surface of MWCNTs.