Cointercalation of titanium dichalcogenides with transition metals and copper

A. A. Titov; A. N. Titov; S. G. Titova; S. V. Pryanichnikov; D. S. Chezganov

doi:10.1134/S1063783417010346

Cointercalation of titanium dichalcogenides with transition metals and copper

作者: Titov A.A.¹, Titov A.N.¹^,2, Titova S.G.³, Pryanichnikov S.V.³, Chezganov D.S.²
隶属关系:
1. Institute of Metal Physics, Ural Branch
2. Ural Federal University
3. Institute of Metallurgy, Ural Branch
期: 卷 59, 编号 1 (2017)
页面: 145-150
栏目: Phase Transitions
URL: https://bakhtiniada.ru/1063-7834/article/view/199538
DOI: https://doi.org/10.1134/S1063783417010346
ID: 199538

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Сointerсalated materials are studied, obtained by introducing copper into a TiSe₂ lattice preintercalated with transition metals M = Mn, Fe, Co, or Ni. The analysis of the state of cointercalated systems at 950°C shows that copper reduces manganese and iron, but it is incapable of reducing cobalt or nickel. To explain the results, the values of the binding energy of hybrid states M3d/Ti3d are compared.