Partial conductivities in perovskites CaZr1–xScxO3–α (x = 0.03–0.20) in an oxidation atmosphere


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Abstract

Partial (ionic, proton, and hole) conductivities of oxides CaZr1–xScxO3–α(x = 0.03–0.20) with the perovskite structure in air atmosphere have been studied as functions of temperature in the range of 600–900°C and partial water-vapor pressure in the range of \({P_{{H_2}O}}\)= 40–2500 Pa. The influence of the humidity of the atmosphere on the relative change in the concentration of oxygen vacancies as a function of temperature has been estimated.

About the authors

V. P. Gorelov

Institute of High-Temperature Electrochemistry, Ural Branch

Author for correspondence.
Email: gorelov@ihte.uran.ru
Russian Federation, ul. Akademicheskaya 20, Yekaterinburg, 620137

V. B. Balakireva

Institute of High-Temperature Electrochemistry, Ural Branch

Email: gorelov@ihte.uran.ru
Russian Federation, ul. Akademicheskaya 20, Yekaterinburg, 620137

A. V. Kuz’min

Institute of High-Temperature Electrochemistry, Ural Branch; Ural Federal University

Email: gorelov@ihte.uran.ru
Russian Federation, ul. Akademicheskaya 20, Yekaterinburg, 620137; ul. Mira 19, Yekaterinburg, 620002

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