Purpurite from spodumene pegmatite of Kolmozero deposit, Kola Peninsula, Russia

L. M. Lyalina; Лялина Л. М.; E. A. Selivanova; Селиванова Е. А.; A. A. Zolotarev; Золотарев А. А.; Ye. E. Savchenko; Савченко Е. Э.; A. A. Kompanchenko; Компанченко А. А.

doi:10.31857/S0869605524050061

Purpurite from spodumene pegmatite of Kolmozero deposit, Kola Peninsula, Russia

作者: Lyalina L.M.¹, Selivanova E.A.¹, Zolotarev A.A.², Savchenko Y.E.¹, Kompanchenko A.A.¹
隶属关系:
1. Federal Research Centre Kola Science Centre, RAS
2. Saint Petersburg State University
期: 卷 CLIII, 编号 5 (2024)
页面: 111-126
栏目: МИНЕРАЛЫ И ПАРАГЕНЕЗИСЫ МИНЕРАЛОВ
URL: https://bakhtiniada.ru/0869-6055/article/view/281293
DOI: https://doi.org/10.31857/S0869605524050061
EDN: https://elibrary.ru/PCEHQI
ID: 281293

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Purpurite Mn³⁺(PO₄) from the spodumene pegmatite of the Kolmozero deposit, Kola Peninsula, Russian Arctic, was studied comprehensively, which allowed to obtain the data about its morphology, mineral assemblage, chemical composition and crystal structure. The Raman spectrum of the mineral was also obtained. Purpurite occur as powdery aggregates on crystal surfaces and cleavage planes of lithiophilite and spodumene, as well as patches among of secondary mineral masses filling the cavities in pegmatite. Purpurite from Kolmozero has high iron content with Mn/(Mn+Fe) ≈ 0.55. Its composition is close to the isomorphic heterosite Fe³⁺(PO₄). The crystal structure of natural purpurite has been studied for the first time in this work. Purpurite is orthorhombic, space group Pbnm, unit cell parameters: a = 4.7783(3), b = 9.7417(5), c = 5.8388(4) Å, V = 271.79(3) Å³, R₁ = 2.42 %. The crystal structure of purpurite is based upon layers of vertex-sharing octahedra (Mn³⁺, Fe³⁺)O₆ that linked via PO₄ tetrahedra. The (Mn³⁺, Fe³⁺)O₆ octahedra are strongly distorted.

关键词

purpurite, triphylite group minerals, crystal structure, spodumene pegmatite, Kolmozero deposit, Kola Peninsula, Russian Arctic

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俄罗斯联邦, Apatity

参考

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2. Fig. 1. The location of the Kolmozero lithium deposit within the Kolmozero-Voronya zone (a) and geological scheme of deposit (б).

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3. Fig. 2. Composition of tripohylite group minerals from Kolmozero deposit, Kola Peninsula, Russia: 1, 2 — lithiophilite, 3 — heterosite, 4 — purpurite.

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4. Fig. 3. The crystal structure of purpurite. Projection to the bc plane. The (Mn3+, Fe3+)O6 octahedra are violet, PO4 tetrahedra are grey (а); the coordination of (Mn3+, Fe3+)O6 octahedra and PO4 tetrahedra (б).