Purpurite from spodumene pegmatite of Kolmozero deposit, Kola Peninsula, Russia
- 作者: Lyalina L.M.1, Selivanova E.A.1, Zolotarev A.A.2, Savchenko Y.E.1, Kompanchenko A.A.1
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隶属关系:
- Federal Research Centre Kola Science Centre, RAS
- Saint Petersburg State University
- 期: 卷 CLIII, 编号 5 (2024)
- 页面: 111-126
- 栏目: МИНЕРАЛЫ И ПАРАГЕНЕЗИСЫ МИНЕРАЛОВ
- URL: https://bakhtiniada.ru/0869-6055/article/view/281293
- DOI: https://doi.org/10.31857/S0869605524050061
- EDN: https://elibrary.ru/PCEHQI
- ID: 281293
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详细
Purpurite Mn3+(PO4) from the spodumene pegmatite of the Kolmozero deposit, Kola Peninsula, Russian Arctic, was studied comprehensively, which allowed to obtain the data about its morphology, mineral assemblage, chemical composition and crystal structure. The Raman spectrum of the mineral was also obtained. Purpurite occur as powdery aggregates on crystal surfaces and cleavage planes of lithiophilite and spodumene, as well as patches among of secondary mineral masses filling the cavities in pegmatite. Purpurite from Kolmozero has high iron content with Mn/(Mn+Fe) ≈ 0.55. Its composition is close to the isomorphic heterosite Fe3+(PO4). The crystal structure of natural purpurite has been studied for the first time in this work. Purpurite is orthorhombic, space group Pbnm, unit cell parameters: a = 4.7783(3), b = 9.7417(5), c = 5.8388(4) Å, V = 271.79(3) Å3, R1 = 2.42 %. The crystal structure of purpurite is based upon layers of vertex-sharing octahedra (Mn3+, Fe3+)O6 that linked via PO4 tetrahedra. The (Mn3+, Fe3+)O6 octahedra are strongly distorted.
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作者简介
L. Lyalina
Federal Research Centre Kola Science Centre, RAS
编辑信件的主要联系方式.
Email: l.lyalina@ksc.ru
Geological Institute
俄罗斯联邦, ApatityE. Selivanova
Federal Research Centre Kola Science Centre, RAS
Email: l.lyalina@ksc.ru
Geological Institute
俄罗斯联邦, ApatityA. Zolotarev
Saint Petersburg State University
Email: l.lyalina@ksc.ru
Institute of Earth Sciences
俄罗斯联邦, Saint PetersburgYe. Savchenko
Federal Research Centre Kola Science Centre, RAS
Email: l.lyalina@ksc.ru
Geological Institute
俄罗斯联邦, ApatityA. Kompanchenko
Federal Research Centre Kola Science Centre, RAS
Email: l.lyalina@ksc.ru
Geological Institute
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