Composite photocatalysts Cd1–xZnxS/TiO2 for hydrogen evolution from aqueous solutions of organic and inorganic sacrificial agents

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Abstract

The photocatalytic activity of Cd1–xZnxS (x = 0–1) and TiO2/Cd1–xZnxS composites in the reaction of hydrogen evolution under visible light irradiation (λ = 410 nm) was studied. In the system with an aqueous solution of C2H5OH used as a sacrificial agent, the maximum activity (1.6 mmol g–1 h–1) was demonstrated by Cd0.1Zn0.9S. When using 0.1 M Na2S/0.1 M Na2SO3 as a sacrificial additive, the activity of all Cd1–xZnxS photocatalysts significantly increased, reaching a maximum of 7.0 mmol g–1 h–1 in the presence of Cd0.3Zn0.7S. The deposition of 1% TiO2 on Cd0.3Zn0.7S by mixing in acetone made it possible to synthesize a highly effective composite with an activity of 8.3 mmol g–1 h–1, which corresponds to the world level. A key result is confirmation of the high stability of this composite in both organic and inorganic environments, opening up prospects for its practical application in photocatalytic hydrogen evolution.

About the authors

A. V Zhurenok

Federal Research Center Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

N. Bu

Novosibirsk National Research State University; Heilongjiang University

Novosibirsk, Russia; Harbin China

D. D Mishchenko

Federal Research Center Boreskov Institute of Catalysis SB RAS; Multiaccess Center "SKIF" Boreskov Institute of Catalysis

Koltsovo, Russia

E. Yu Gerasimov

Federal Research Center Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

E. A Kozlova

Federal Research Center Boreskov Institute of Catalysis SB RAS

Email: kozlova@catalysis.ru
Novosibirsk, Russia

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