SYNTHESIS AND PPOPERTIES OF ZNO/ZNWO4 NANOCOMPOSITES FOR PHOTOELECTROCHEMICAL APPLICATIONS:

A. A. Ulyankina; Ульянкина А. А.; A. D. Tsarenko; Царенко А. Д.; T. A. Molodtsova; Молодцова Т. А.; M. V. Gorshenkov; Горшенков М. В.; N. V. Smirnova; Смирнова Н. В.

doi:10.31857/S0424857023120149

Нанокомпозиты ZnO/ZnWO₄ для фотоэлектрохимических приложений: синтез и свойства

Авторы: Ульянкина А.А.¹, Царенко А.Д.¹, Молодцова Т.А.¹, Горшенков М.В.², Смирнова Н.В.¹
Учреждения:
1. Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова
2. Национальный исследовательский технологический университет “МИСИС”
Выпуск: Том 59, № 12 (2023)
Страницы: 790-797
Раздел: Статьи
URL: https://bakhtiniada.ru/0424-8570/article/view/232690
DOI: https://doi.org/10.31857/S0424857023120149
EDN: https://elibrary.ru/VDTVFT
ID: 232690

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Аннотация

Получена серия нанокомпозитов ZnO/ZnWO₄ с различным содержанием фазы ZnWO₄ на основе нанопорошков ZnO и WO₃, электрохимически синтезированных под действием переменного импульсного тока. Комплексом физико-химических методов (рентгенофазовый анализ, спектроскопия комбинационного рассеяния, просвечивающая электронная микроскопия, энергодисперсионный микроанализ) исследованы состав и структурные характеристики полученных материалов. Определен оптимальный состав нанокомпозита с содержанием ZnWO₄ ~ 6% для использования в качестве фотоанодного материала проточного фототопливного элемента с сульфатным электролитом с добавлением органического и неорганического топлива. Максимальные значения E_oc и P_max, которые составили 850 мВ и 85.8 мкВт/см² соответственно, были достигнуты при использовании Na₂SO₄ c добавлением глюкозы в качестве топлива.

Ключевые слова

ZnO/ZnWO₄, нанокомпозит, фотоэлектрохимическая активность, фототопливный элемент

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