Modification of Quartz Ceramics by Applying a Sol-Gel Composition of MgO–Al2O3–ZrO2–SiO2 System

S. K. Evstrop'ev; Евстропьев С. К; V. M. Volynkin; Волынкин В. М; A. S. Saratovskiy; Саратовский А. С; D. P. Danilovich; Данилович Д. П; V. V. Demidov; Демидов В. В; K. V. Dukel'skiy; Дукельский К. В; D. V. Bulyga; Булыга Д. В.; S. O. Sysolyatin; Сысолятин С. О

doi:10.31857/S0044461823020081

Modification of Quartz Ceramics by Applying a Sol-Gel Composition of MgO–Al2O3–ZrO2–SiO2 System

Authors: Evstrop'ev S.K.¹^,2^,3, Volynkin V.M.², Saratovskiy A.S.³^,4, Danilovich D.P.³, Demidov V.V.², Dukel'skiy K.V.¹^,2, Bulyga D.V.¹^,2, Sysolyatin S.O.²
Affiliations:
1. ITMO University
2. Vavilov State Optical Institute
3. St. Petersburg State Institute of Technological (Technical University)
4. Institute of Silicate Chemistry named after I. V. Grebenshchikov, Russian Academy of Sciences
Issue: Vol 96, No 2 (2023)
Pages: 200-208
Section: Articles
URL: https://bakhtiniada.ru/0044-4618/article/view/247278
DOI: https://doi.org/10.31857/S0044461823020081
EDN: https://elibrary.ru/PBGVPB
ID: 247278

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Composite sol-gel materials of the MgO–Al2O3–ZrO2–SiO2 system were synthesized and the processes of their thermal evolution and crystallization were studied. Application of sol-gel compositions of the MgO–Al2O3–ZrO2–SiO2 system to the surface of quartz ceramics leads to a significant increase in the mechanical strength of the material. The processes of thermal evolution of the sol-gel composition were studied using IR spectroscopy, X-ray diffraction, electron microscopy, and energy dispersive analysis. It was shown that the formation of the oxide composite structure of materials begins at the stage of wet gels. Treatment of quartz ceramics with composite sols followed by drying and heat treatment up to 1200°C results in modification of the surface layers of the material, which makes it possible to increase the mechanical strength of the material by more than 20%. Sol-gel modifying compositions, upon drying and subsequent heat treatment, form polycrystalline structures bonded to quartz ceramic particles and consisting of various oxide crystals.

Keywords

quartz ceramics, sol-gel, mechanical strength, crystals, MgO–Al2O3–ZrO2–SiO2, glaze

References

Pivinskii Yu. E., Tsarev V. F., Tereshchenko Z. E., Koneva L. S. The slip casting rate for quartz ceramics // Refractories. 1973. V. 14. P. 509-512. https://doi.org/10.1007/BF01284421
Xu H., Liu J., Guo A., Du H., Hou Z. Porous silica ceramics with relatively high strength and novel bi-modal pore structure prepared by a tba-based gel-casting method // Ceram.Int. 2011. V. 38. N 2. P. 1725-1729. https://doi.org/10.1016/j.ceramint.2011.09.013
Dehghani P., Soleimani F. Effect of cristobalite content on physical, dielectric constant, and bending strength of fused silica ceramics formed by slip casting method // Advanced Ceram. Progr. 2021. V. 7. N 22. P. 16-22. https://doi.org/10.30501/ACP.2021.286931.1060
Wan Wei, Huang Chun-e, Yang Jian, Zheng Jinzhen, Qiu Tai. Effect of sintering temperature on the properties of fused silica ceramics prepared by gel casting //j. Electron. Mater. 2014. V. 43. P. 2566-2569. https://doi.org/10.1007/s11664-014-3112-7
Casasola R., Ma Rincón J., Romero M. Glass-ceramic glazes for ceramic tiles: A Review //j. Mater. Sci. 2012. V. 47. P. 553-582. https://doi.org/10.1007/s10853-011-5981-y
Kaya G., Karasu B. ZrO2-CaO-MgO-SiO2 (ZrCMS) system glass-ceramic glazes suitable for porcelain tiles // Proceeding of Austceram & The 3rd Int. Conf. of Advanced Materials Processing. 2004. P. 301-302.
Ferrari A. M., Barbieri L., Leonelli C., Manfredeni T., Siligardi C., Corradi A. B. Feasibility of using cordierite glass-ceramics as tile glazes. //j. Am. Ceram. Soc. 1997. V. 80. N 7. P. 1757-1766. https://doi.org/10.1111/j.1151-2916.1997.tb03049.x
Bondioli F., Taurino R., Ferrari A. M. Functionalization of ceramic tile surface by sol-gel //j. Colloid Interf. Sci. 2009. V. 334. N 2. P. 195-201. https://doi.org/10.1016/j.jcis.2009.02.054
Pasiut K., Partyka J., Lesniak M. Jelen P., Olejniczak Z. Raw glass-ceramics glazes from SiO2-Al2O3-CaO-MgO-Na2O-K2O system modified by ZrO2 addition - Changes of structure, microstructure and surface properties // Open Ceram. 2021. V. 8. 100188. https://doi.org/10.1016/j.oceram.2021.100188
Евстропьев С. К., Волынкин В. М., Шашкин А. В., Гатчин Ю. А., Дукельский К. В., Коробейников А. Г., Поляков В. И. Влияние одностадийной обработки кварцевой керамики гелеобразующими растворами на прочностные характеристики // Науч.-техн. вестн. информационных технологий, механики, оптики. 2014. № 5. C. 46-51.
Liu B., Gao M., Liu X., Zhao X., Zhang J., Yi X. Thermal stable nanoporous ZrO2/SiO2 HYBRID aerogels for thermal insulation // ACS Appl. Nano Mater. 2019. V. 2. N 11. P. 7299-7310. https://doi.org/10.1021/acsanm.9b01791
Gorelova A. V., Evstropiev S. K., Efremov A. M., Konovalov A. V., Petrovskii G. T., Semenov A. D., Shashkin V. S. Inorganic sol-gel synthesis of monolithic silica glasses with the use of aerosils // Glass Phys. Chem. 1999. V. 25. N 3. P. 274-280.
Adachi T., Sakka S. The Role of N,N-dimethylformamide, A DCCA, in the formation of silica gel monoliths by sol-gel method //j. Non-Cryst. Solids. 1988. V. 99. N 1. P. 118-128. https://doi.org/10.1016/0022-3093(88)90464-4.
Bortkevich A. V., Dymshits O. S., Zhilin A. A., Polushkin A. Yu., Tsenter M. Ya., Shashkin A. V., Golubkov V. V., Bʹen V.-B., Li K.-K., Pak E.-B. Study of phase transformation in titanium-containing magnesium-aliminum silicate glasses and glass-ceramics for diffuse reflectors //j. Opt. Technol. 2002. V. 69. N 8. P. 558-594. https://doi.org/10.1364/JOT.69.000588
Zandonà A., Moustrous M., Véron C. G. E., Canizarès A., Allix M. Glass-forming ability and ZrO2 saturation limits in the magnesium aluminosilicate system // Ceram.Int. Elsevier, 2021. hal-03478059f. https://doi.org/10.1016/j.ceramint.2021.12.051
Petrović R., Janaćkocić D., Zec, S., Drmanić S. Ž., Kostić-Gvozdenović L. J. Crystallization behavior of alkoxy-derived cordierite gels //j. Sol-Gel Sci. Technol. 2003. V. 28. N 1. P. 111-118. https://doi.org/10.1023/1025649406466
Tsai M.-T. Synthesis of nanocrystalline enstatite fiber via alkoxide sol-gel process //j. Am. Ceram. Soc. 2005. V. 88. N 7. P. 1770-1772. https://dx.doi.org/10.1111/j.1551-2916.2005.00359.x
Pagliari L., Dapiaggi M., Pavese A., Francescon F. A Kinetic study of the quartz-crystobalite phase transition //j. Eur. Ceram. Soc. 2013. V. 33. N 15. P. 3403-3410. https://dx.doi.org/10.1016/j.jeurceramsoc.2013.06.014
Lange P. Evidence for disorder-induced vibration mode coupling in thin amorphous sio2 films //j. Appl. Phys. 1989. V. 66. 201. https://dx.doi.org/10.1063/1.344472
Borrajo J. P., Liste S., Serra J., González P., Chiussi S., León B., Pérez-Amor M., Ylänen H. O., Hupa M. Influence of the network modifier content on the bioactivity of silicate glasses // Key Eng. Mater. 2004. V. 254-256. P. 23-26. https://doi.org/10.4028/www/scientific.net/KEM.254-256.23
Damayanti N. P. Preparation of superhydrophobic pet fabric from Al2O3-SiO2 hybrid: Geometrical approach to create high contact angle surface from low contact angle materials //j. Sol-Gel Technol. 2010. V. 56. P. 47-52. https://doi.org/10.1007/s10971-010-2271-0
Ficheux M., Burov E., Aquilanti G., Trcera N., Montouillout V., Cormier L. Structural evolution of high zirconia aluminosilicate glasses //j. Non-Cryst. Solids. 2020. V. 539. 120050. https://doi.org/10.1016/j.jnoncrysol.2020.120050
Castro Y., Aparicio M., Moreno R., Durán A. Silica-zirconia sol-gel coating obtained by different synthesis routes //j. Sol-Gel Sci. Technol. 2005. V. 34. P. 1-9. https://doi.org/10.1007/s10971-005-3213-0
Pivinskii Yu. E., Dyakin P. V., Kolobov A. Yu. Research in the area of preparing materials based on fused quartz HCBs. Part 8. Effect of alkali additions on ceramic sintering and cristobalitization in nonisothermal heating regime // Refract. Industr. Ceram. 2016. V. 57. P. 27-32. https://doi.org/10.1007/s11148-016-9921-x

Supplementary files

Supplementary Files

Action

1. JATS XML

Download

Username
Password
Remember me

Forgot password?	Register

Username
Password
Remember me

Forgot password?	Register

Modification of Quartz Ceramics by Applying a Sol-Gel Composition of MgO–Al2O3–ZrO2–SiO2 System

Full Text

Abstract

Keywords

About the authors

References

Supplementary files