Email this article Luminescent Europium(III) Compounds with Quinaldic Acid
- Authors: Kalinovskaya I.V.1
-
Affiliations:
- Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia
- Issue: Vol 96, No 1 (2023)
- Pages: 27-33
- Section: Articles
- URL: https://bakhtiniada.ru/0044-4618/article/view/141697
- DOI: https://doi.org/10.31857/S0044461823010048
- EDN: https://elibrary.ru/HUIBKL
- ID: 141697
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Abstract
Heteroligand luminescent europium(III) complexes with quinaldic acid and neutral ligands were prepared. The compounds obtained were characterized by elemental analysis, X-ray diffraction, thermal gravimetric analysis, and IR spectroscopy. The composition of the complexes was determined. In the course of thermolysis, the nitrogen-containing ligand molecule is eliminated in one step with exo- and endothermic effects. The compounds are thermally stable up to 260°С. The synthesized coordination compounds were introduced into low-density polyethylene to obtain luminescent polymer materials.
About the authors
I. V. Kalinovskaya
Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia
Author for correspondence.
Email: acjournal.nauka.nw@yandex.ru
References
- Bunzli J.-C. G., Eliseeva S. V.Intriguing aspects of lanthanide luminescence // Chem. Sci. 2013. V. 4. P. 1939-1949. https://doi.org/10.1039/C3SC22126A
- Hasegawa Y., Nakanishi T. Luminescent lanthanide coordination polymers for photonic applications // RSC. Adv. 2015. V. 5. P. 338-353. https://doi.org/10.1039/C4RA09255D
- Seminara A., Musumeci A. J. Lanthanide chelates of some quinolinecarbo-хylic acids //j. Inorg. Nucl. Chem. 1977. V. 39. P. 599-605.
- Калиновская И. В. Люминесцентные свойства соединений европия(III) с хинальдиновой кислотой и серосодержащимим нейтральными лигандами // ЖОХ. 2019. Т. 89. № 12. С. 1909-1914. https://doi.org/10.1134/S0044460X19120151
- Калиновская И. В., Мирочник А. Г., Карасев В. E. Фотодеструкция и фотостабилизация соединений европия в поливинилхлориде // ЖПХ. 2008. Т. 81. C. 2073-2075. EDN:KFSRFT
- Калиновская И. В., Буквецкий Б. В. Кристаллическая структура, люминесценция и триболюминесценция комплекса [Eu2(Quin)42H2O2Dipy]2(NO3)2H2O // Опт. и спектр. 2019. Т. 127. № 9. С. 412-419. https://doi.org/10.21883/OS.2019.09.48193.245-18
- St arynowicz P. Structure of bis-m-(2- quinolinecarboxylato-O,O,Oʹ)bis[triaqua-(2- quinolinecarboxylato-N,O)(2-quinolinecarboxylato-O) neodymium(III)] trihydrate // Acta Cryst. 1990. V. 46. P. 2068-2070.
- Bukvetskii B. V., Kalinovskaya I. V. Crystal structure, luminescence and triboluminescence of the complex [Eu(NO3)23hmpa] NO3·HQuin //j. Fluorescence. 2017. V. 27. N 3. P. 773-779. https://doi.:10.1007/s10895-016-2009-7
- Oliveira V. S., Araújo Melo D. M., Rocha da Silva Z., Zinner L. B., Zinner K. Preparation and properties of complexes between rare earth trifluoroacetates and hexamethylphosphoramide (HMPA) //j. Alloys Compd. 2000. V. 303-304. P. 157-161. https://doi.org/10.1016/S0925-8388(00)00658-7
- Калиновская И. В., Задорожная А. Н., Савченко Н. Н. Разнолигандные комплексные соединения европия(III) c 4-метилбензойной кислотой // ЖОХ. 2019. Т. 89. № 11. C. 1780-1785. 10.1134/S0044460X19110192' target='_blank'>https://doi: 10.1134/S0044460X19110192
- Калиновская И. В., Задорожная А. Н., Привар Ю. О. Синтез и строение о-метилбензоатов европия // ЖОХ. 2021. Т. 91. № 2. C. 238-244. https://doi.org/10.31857/S0044460X21020074
- Pimentel P. M., Oliveira V. S., Silva Z. R., Melo D. M. A., Zinner L. B., Vicentini G., Bombieri G. Synthesis, properties of lanthanide trifluoroacetate complexes with 2-azacyclononanone and X-ray crystal structure of [Sm(CF3COO)3(AZA)2(H2O)]2·2AZA //Polyhedron. 2000. V. 19. P. 2651-2657. https://doi.org/10.1016/S0277-5387(01)00868-3
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