SYNTHESIS AND THERMODYNAMIC INVESTIGATIONS OF COMPOUND ON THE BASIS OF BISMUTH AND ITTERBIUM OXIDES
- 作者: Matskevich N.I.1, Elbaev E.R.1,2, Semerikova A.N.1, Manakov A.Y.1, Levchenko L.M.1, Shapovalova A.A.1, Zaitsev V.P.3, Tkachev E.N.1
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隶属关系:
- Nikolaev Institute of Inorganic Chemistry SB RAS
- Novosibirsk State Technical University
- Siberian State University of Water Transport
- 期: 卷 70, 编号 8 (2025)
- 页面: 1076-1080
- 栏目: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
- URL: https://bakhtiniada.ru/0044-457X/article/view/308584
- DOI: https://doi.org/10.31857/S0044457X25080111
- EDN: https://elibrary.ru/jjqvhw
- ID: 308584
如何引用文章
详细
In the paper, compound with composition Bi1.3Yb0.7O3 was prepared by solid state reactions. It was shown that compound had cubic structure, space group Fm3m, lattice parameter a = 0.54202 nm. The dissolution enthalpy of compound Bi1.3Yb0.7O3 was measured by solution calorimetry in 2 M HCl and was ∆solH0 = −227.8 ± 6.3 kJ mol−1. Based on measured enthalpy of dissolution, the standard formation enthalpy of Bi1.3Yb0.7O3 was calculated as following value: ∆fH0 = −996.0 ± 7.9 kJ mol −1. Using Born-Haber cycle, the lattice enthalpy for Bi1.3Yb0.7O3 was calculated: ∆latH0 = −13278 kJ mol−1.
作者简介
N. Matskevich
Nikolaev Institute of Inorganic Chemistry SB RAS
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia
E. Elbaev
Nikolaev Institute of Inorganic Chemistry SB RAS; Novosibirsk State Technical University
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia; Karl Marks Avenue, 20, Novosibirsk, 630073 Russia
A. Semerikova
Nikolaev Institute of Inorganic Chemistry SB RAS
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia
A. Manakov
Nikolaev Institute of Inorganic Chemistry SB RAS
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia
L. Levchenko
Nikolaev Institute of Inorganic Chemistry SB RAS
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia
A. Shapovalova
Nikolaev Institute of Inorganic Chemistry SB RAS
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia
V. Zaitsev
Siberian State University of Water Transport
Email: nata.matskevich@yandex.ru
Shchetinkina Avenue, 33, Novosibirsk, 630033 Russia
E. Tkachev
Nikolaev Institute of Inorganic Chemistry SB RAS
编辑信件的主要联系方式.
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia
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