On the Applicability of a Quasi-Stationary Solution of the Diffusion Equation for the Hydrate Layer Formed at the Gas–Ice (Water) Interface

Resumo

The problem of methane hydrate formation when the process is controlled by gas diffusion in the hydrate layer formed at the gas–ice (or water) interface is solved. It is shown that an approximate quasi-stationary solution of the diffusion equation is in good agreement with its numerical solution over a wide range of the solubility of the gas in the hydrate, which is dependent on pressure. It is found that the time for the complete transition of the water (or ice) phase into the hydrate state decreases with an increase in the saturation concentration of the mobile gas in the hydrate. The kinetic equations derived based on a quasi-stationary solution of the diffusion equation, which are relationships for the intensity of hydrate formation in snow-containing (or water-containing) formations during the filtration of hydrate-forming gases, are used to describe the concentration fields of the diffusing gas and the dynamics of hydrate layer growth.