Spectroscopic Study of the Semihydrate of the Dodecahydro- closo -dodecaborate of 2,4,6-Triamino-1,3,5-triazine

V. I. Saldin; A. B. Slobodyuk; N. N. Savchenko; L. N. Ignat’eva; V. M. Buznik

doi:10.1134/S0036024418110353

Spectroscopic Study of the Semihydrate of the Dodecahydro-closo-dodecaborate of 2,4,6-Triamino-1,3,5-triazine

作者: Saldin V.I.¹, Slobodyuk A.B.¹, Savchenko N.N.¹, Ignat’eva L.N.¹, Buznik V.M.¹
隶属关系:
1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences
期: 卷 92, 编号 11 (2018)
页面: 2210-2214
栏目: Structure of Matter and Quantum Chemistry
URL: https://bakhtiniada.ru/0036-0244/article/view/170205
DOI: https://doi.org/10.1134/S0036024418110353
ID: 170205

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详细

The presence of directed localized cation–anion interactions in the semihydrate of 2,4,6-triamino-1,3,5-triazine (melamine) dodecahydro-closo-dodecaborate (С₃Н₆N₆Н)₂В₁₂Н₁₂ · 0.5Н₂О is discovered by means of IR and NMR-spectroscopy (¹¹В, ¹Н, С, N). The hypothesis that melamine protonation proceeds on the ring atom of nitrogen is confirmed via quantum-chemical calculations.