Interaction between Peroxy Radicals and Acetaldehyde on Solid Surfaces and Its Role in the Oxidation of Aldehydes


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Heterogeneous interaction between peroxy radicals and acetaldehyde in a capillary reactor treated with boric acid was studied. The possibility of a reaction occurring between adsorbed peroxy radicals and acetaldehyde was confirmed. Based on a comparison of these data and those obtained for other surfaces along with the ignition and slow oxidation of aldehydes in reactors with identical surfaces, it was concluded that the oxidation of aldehydes includes not only a homogeneous component but a heterogeneous component as well.

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I. Vardanyan

Nalbandyan Institute of Chemical Physics

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Email: ivardan@ichph.sci.am
亚美尼亚, Yerevan, 0014

A. Arustamyan

Nalbandyan Institute of Chemical Physics

Email: ivardan@ichph.sci.am
亚美尼亚, Yerevan, 0014

A. Martirosyan

Nalbandyan Institute of Chemical Physics

Email: ivardan@ichph.sci.am
亚美尼亚, Yerevan, 0014

S. Tsarukyan

Nalbandyan Institute of Chemical Physics

Email: ivardan@ichph.sci.am
亚美尼亚, Yerevan, 0014

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