Отправить статью по E-mail Kinetic and thermodynamic parameters of hydrogen release during the heterogeneous catalytic dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl
- Авторы: Kalenchuk A.N.1,2, Bogorodskii S.E.3, Bogdan V.I.1,2
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Учреждения:
- Department of Chemistry
- Zelinsky Institute of Organic Chemistry
- Advanced Laser Technologies Division, Institute of Laser and Information Technologies
- Выпуск: Том 90, № 10 (2016)
- Страницы: 1921-1924
- Раздел: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/168803
- DOI: https://doi.org/10.1134/S0036024416100162
- ID: 168803
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Аннотация
Comparative studies on the temperature dependence of the dehydrogenation of cis- and trans-isomers of perhydro-m-terphenyl are performed in a flow catalytic reactor. Rate constants and equilibrium constants of all elementary acts of this reaction are calculated on basis of experimental data using the KINET 0.8 program for the mathematical modeling of the kinetics of complex reactions. The resulting data indicate that perhydro-m-terphenyl cis- and trans-isomers structural differences have no appreciable effect on dehydrogenation.
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Об авторах
A. Kalenchuk
Department of Chemistry; Zelinsky Institute of Organic Chemistry
Автор, ответственный за переписку.
Email: akalenchuk@yandex.ru
Россия, Moscow, 119991; Moscow, 119991
S. Bogorodskii
Advanced Laser Technologies Division, Institute of Laser and Information Technologies
Email: akalenchuk@yandex.ru
Россия, Troitsk, Moscow oblast, 142092
V. Bogdan
Department of Chemistry; Zelinsky Institute of Organic Chemistry
Email: akalenchuk@yandex.ru
Россия, Moscow, 119991; Moscow, 119991
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