Отправить статью по E-mail Sorbents based on asbestos with a layer of an hydroxyethylcyclam derivative of PVC containing aquacomplexes of sulfuric acid or sodium hydroxide with aza-crown groups
- Авторы: Tsivadze A.Y.1, Fridman A.Y.1, Morozova E.M.1, Sokolova N.P.1, Voloshchuk A.M.1, Petukhova G.A.1, Bardyshev I.I.1, Gorbunov A.M.1, Polyakova I.Y.1, Titova V.N.1, Yavich A.A.1, Novikov A.K.1, Petrova N.V.1
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Учреждения:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 90, № 7 (2016)
- Страницы: 1456-1460
- Раздел: Physical Chemistry of Surface Phenomena
- URL: https://bakhtiniada.ru/0036-0244/article/view/168493
- DOI: https://doi.org/10.1134/S0036024416070323
- ID: 168493
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Аннотация
Aquacomplexes of sulfuric acid and sodium hydroxide with aza-crown groups are synthesized in cavities of a sorbent from the porous layer of a PVC cyclam-derivative grafted onto fibers of asbestos fabric. The structure of sorbents with complexes is studied and their adsorption characteristics are determined. It is shown that the affinity of the developed surface toward ethanol, benzene, and hexane depends on the nature of complexes in the pore walls, and the volume of cavities formed as a result of the pores on the developed asbestos surface being coated with networks of aza-crown groups is larger than that of cavities with walls of aza-crown groups in the layers of a PVC cyclam derivative. Indicators of H+- and OH–-conductivity of sorbents with complexes as electrochemical bridges are determined. It is shown that the major part of H+- and OH–-ions moves through complexes with aza-crown groups in the region of cavities formed of pores on the surface of asbestos.
Об авторах
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Автор, ответственный за переписку.
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
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