Отправить статью по E-mail Solubility of Tetra(pyrid-3- and 4-yl)porphines and Their Complexes with d-Metals in Chloroform and Ethanol
- Авторы: Berezina N.M.1, Berezin M.B.2
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Учреждения:
- Ivanovo State University of Chemistry and Technology
- G. A. Krestov Institute of Solution Chemistry of Russian Academy of Sciences
- Выпуск: Том 90, № 4 (2016)
- Страницы: 787-791
- Раздел: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0244/article/view/168037
- DOI: https://doi.org/10.1134/S003602441604004X
- ID: 168037
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Аннотация
The solubility of 5,10,15,20-tetra(pyrid-3- and 4-yl)porphine isomers and their coordination compounds with d-metals in the temperature range of 298–318 K is studied. Patterns of the dissolving of porphyrin ligands and the metal complexes they form with Co(II), Cu(II), and Zn(II) in chloroform and ethanol depending on the nature of the metal and the position of the nitrogen atom in the pyridyl substituent of the porphyrin molecule are discussed. The thermodynamic parameters of dissolution are calculated for the investigated compounds.
Об авторах
N. Berezina
Ivanovo State University of Chemistry and Technology
Автор, ответственный за переписку.
Email: sky_berezina@rambler.ru
Россия, Ivanovo, 153000
M. Berezin
G. A. Krestov Institute of Solution Chemistry of Russian Academy of Sciences
Email: sky_berezina@rambler.ru
Россия, Ivanovo, 153045
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