Ruthenium(III) catalyzed oxidation of sugar alcohols by dichloroisocyanuric acid—A kinetic study
- Авторы: Lakshman Kumar Y.1, Venkata Nadh R.2, Radhakrishnamurti P.S.1
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Учреждения:
- Department of Chemistry
- GITAM University — Bengaluru Campus
- Выпуск: Том 90, № 2 (2016)
- Страницы: 300-307
- Раздел: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/167695
- DOI: https://doi.org/10.1134/S0036024416020163
- ID: 167695
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Аннотация
Kinetics of ruthenium(III) catalyzed oxidation of biologically important sugar alcohols (myo-inositol, D-sorbitol, and D-mannitol) by dichloroisocyanuric acid was carried out in aqueous acetic acid—perchloric medium. The reactions were found to be first order in case of oxidant and ruthenium(III). Zero order was observed with the concentrations of sorbitol and mannitol whereas, a positive fractional order was found in the case of inositol concentration. An inverse fractional order was observed with perchloric acid in oxidation of three substrates. Arrhenius parameters were calculated and a plausible mechanism was proposed.
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Y. Lakshman Kumar
Department of Chemistry
Email: doctornadh@yahoo.co.in
Индия, Guntur, 522006
R. Venkata Nadh
GITAM University — Bengaluru Campus
Автор, ответственный за переписку.
Email: doctornadh@yahoo.co.in
Индия, Karnataka, 561 203
P. Radhakrishnamurti
Department of Chemistry
Email: doctornadh@yahoo.co.in
Индия, Guntur, 522006
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