🔧На сайте запланированы технические работы
25.12.2025 в промежутке с 18:00 до 21:00 по Московскому времени (GMT+3) на сайте будут проводиться плановые технические работы. Возможны перебои с доступом к сайту. Приносим извинения за временные неудобства. Благодарим за понимание!
🔧Site maintenance is scheduled.
Scheduled maintenance will be performed on the site from 6:00 PM to 9:00 PM Moscow time (GMT+3) on December 25, 2025. Site access may be interrupted. We apologize for the inconvenience. Thank you for your understanding!

 

Temperature and concentration dependences of the activity coefficients of electrolytes


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A model has been suggested that describes the interaction of hydrated ions in electrolytes and allows the calculation of the main physical effects. The model explains the character of the curves of the activity coefficients. Binary solutions of uni-univalent electrolytes at concentrations from zero to several moles per liter and at temperatures from zero to a few dozens of degrees were studied. The results of simulation were verified by comparing them with many literature data.

About the authors

N. A. Tikhonov

Faculty of Physics

Author for correspondence.
Email: niktandr@yandex.ru
Russian Federation, Moscow, 119991

G. B. Sidel’nikov

Faculty of Physics

Email: niktandr@yandex.ru
Russian Federation, Moscow, 119991

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2017 Pleiades Publishing, Ltd.