Tri-n-butyl phosphate–ionic liquid mixtures for Li+ extraction from Mg2+-containing brines at 303–343 K
- Autores: Shi C.1,2, Jing Y.1, Jia Y.1
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Afiliações:
- Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes
- University of Chinese Academy of Sciences
- Edição: Volume 91, Nº 4 (2017)
- Páginas: 692-696
- Seção: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0244/article/view/169407
- DOI: https://doi.org/10.1134/S0036024417040033
- ID: 169407
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Resumo
Extraction of Li+ ions from salt lake brine into an ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2mim][NTf2]) mixed with tri-n-butyl was investigated. The extraction mechanism was been studied using UV–Vis spectroscopy From the temperature dependence data, the thermodynamic functions values (ΔG°, ΔH°, and ΔS°) were calculated. Furthermore, stripping of metals from ionic liquid phase to an aqueous phase by hydrochloric acid was accomplished.
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Sobre autores
Chenglong Shi
Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes; University of Chinese Academy of Sciences
Email: 3164034367@qq.com
República Popular da China, Xining, 810008; Beijing, 100049
Yan Jing
Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes
Email: 3164034367@qq.com
República Popular da China, Xining, 810008
Yongzhong Jia
Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes
Autor responsável pela correspondência
Email: 3164034367@qq.com
República Popular da China, Xining, 810008
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