Physicochemical properties of the surfaces of silica species
- Autores: Roshchina T.M.1, Shoniya N.K.1, Tegina O.Y.1, Tkachenko O.P.2, Kustov L.M.1,2
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Afiliações:
- Department of Chemistry
- Zelinsky Institute of Organic Chemistry
- Edição: Volume 91, Nº 2 (2017)
- Páginas: 217-225
- Seção: Nanomaterials and Environment
- URL: https://bakhtiniada.ru/0036-0244/article/view/169218
- DOI: https://doi.org/10.1134/S003602441702025X
- ID: 169218
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Resumo
The results from studying the physicochemical characteristics of the adsorption of n-alkanes, arenes, and acetonitrile on silicas of different origins, silica gels, and silochromes are presented. It is shown that increasing the concentration of silanol groups reduces the role of dispersion interactions accompanied by the intensification of specific interactions on silica gels, compared to silochromes. According to diffuse reflectance FTIR spectroscopy data, the acidity of silanol groups on silica gel is in this case less pronounced.
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Sobre autores
T. Roshchina
Department of Chemistry
Autor responsável pela correspondência
Email: 2474747@mail.ru
Rússia, Moscow, 119992
N. Shoniya
Department of Chemistry
Email: 2474747@mail.ru
Rússia, Moscow, 119992
O. Tegina
Department of Chemistry
Email: 2474747@mail.ru
Rússia, Moscow, 119992
O. Tkachenko
Zelinsky Institute of Organic Chemistry
Email: 2474747@mail.ru
Rússia, Moscow, 119991
L. Kustov
Department of Chemistry; Zelinsky Institute of Organic Chemistry
Email: 2474747@mail.ru
Rússia, Moscow, 119992; Moscow, 119991
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