Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions
- Autores: Bogdan V.I.1,2, Koklin A.E.1, Kozak D.O.1, Kustov L.M.1,2
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Afiliações:
- Zelinsky Institute of Organic Chemistry
- Department of Chemistry
- Edição: Volume 90, Nº 12 (2016)
- Páginas: 2352-2357
- Seção: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/169014
- DOI: https://doi.org/10.1134/S0036024416120050
- ID: 169014
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Resumo
The reduction of carbon dioxide with hydrogen on metal–carbon (Ru, Rh, Ir) catalysts is investigated under supercritical conditions for the first time. High selectivity (close to 100%) toward methanation with good stability of catalytic activity is observed for Ru- and Rh-containing catalyst, while the preferred reduction to CO is observed for Ir/C catalyst.
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Sobre autores
V. Bogdan
Zelinsky Institute of Organic Chemistry; Department of Chemistry
Email: lmk@ioc.ac.ru
Rússia, Moscow, 119991; Moscow, 119991
A. Koklin
Zelinsky Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Rússia, Moscow, 119991
D. Kozak
Zelinsky Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Rússia, Moscow, 119991
L. Kustov
Zelinsky Institute of Organic Chemistry; Department of Chemistry
Autor responsável pela correspondência
Email: lmk@ioc.ac.ru
Rússia, Moscow, 119991; Moscow, 119991
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