Email this article Conditions for the Formation of Microporous Metal–Organic Framework Mil-53(Al)
- Authors: Isaeva V.I.1,2, Chernyshev V.V.3,4, Tarasov A.L.1,2, Lobova A.A.3, Kapustin G.I.1, Davshan N.A.1
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Affiliations:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- National University of Science and Technology (MISiS)
- Department of Chemistry, Moscow State University
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 92, No 12 (2018)
- Pages: 2386-2390
- Section: Physical Chemistry of Hybrid Nanomaterials and Multicomponent Systems
- URL: https://bakhtiniada.ru/0036-0244/article/view/170236
- DOI: https://doi.org/10.1134/S0036024418120166
- ID: 170236
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Abstract
Conditions of crystallization are determined for the MIL-53 (Al) (AlOHbdc, bdc = benzene-1,4-dicarboxylate) microporous metal–organic framework. Three major factors responsible for the formation of a pure phase of MIL-53(Al) are identified. These include the temperature (above ~120°С) and the nature of the solvent. It is established through powder diffraction that using microwave radiation for the activation of the reaction mass leads to the formation of a material with higher phase purity, in contrast to preparation techniques that employ conventional heating (hydrothermal synthesis and synthesis under atmospheric pressure).
About the authors
V. I. Isaeva
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National University of Science and Technology (MISiS)
Author for correspondence.
Email: sharf@ioc.ac.ru
Russian Federation, Moscow, 119991; Moscow, 119991
V. V. Chernyshev
Department of Chemistry, Moscow State University; Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences
Author for correspondence.
Email: vladimir@struct.chem.msu.ru
Russian Federation, Moscow, 119234; Moscow, 119071
A. L. Tarasov
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; National University of Science and Technology (MISiS)
Email: vladimir@struct.chem.msu.ru
Russian Federation, Moscow, 119991; Moscow, 119991
A. A. Lobova
Department of Chemistry, Moscow State University
Email: vladimir@struct.chem.msu.ru
Russian Federation, Moscow, 119234
G. I. Kapustin
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
Russian Federation, Moscow, 119991
N. A. Davshan
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
Russian Federation, Moscow, 119991
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