Algorithm for Calculating the Dissociation Constants of Ampholytes in Nonbuffer Systems
- Авторлар: Lysova S.S.1, Skripnikova T.A.1, Zevatskii Y.E.1,2,3
-
Мекемелер:
- St. Petersburg State University of Industrial Technologies and Design
- ZAO Novbytkhim
- St. Petersburg State Electrotechnical University (LETI)
- Шығарылым: Том 92, № 5 (2018)
- Беттер: 922-926
- Бөлім: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0244/article/view/169999
- DOI: https://doi.org/10.1134/S0036024418050229
- ID: 169999
Дәйексөз келтіру
Аннотация
An algorithm for calculating the dissociation constants of ampholytes in aqueous solutions is developed on the basis of spectrophotometric data in the UV and visible ranges without pH measurements of a medium and without buffer solutions. The proposed algorithm has been experimentally tested for five ampholytes of different strengths. The relative error of measuring dissociation constants is less than 5%.
Авторлар туралы
S. Lysova
St. Petersburg State University of Industrial Technologies and Design
Хат алмасуға жауапты Автор.
Email: lusovass@mail.ru
Ресей, St. Petersburg, 191186
T. Skripnikova
St. Petersburg State University of Industrial Technologies and Design
Email: lusovass@mail.ru
Ресей, St. Petersburg, 191186
Yu. Zevatskii
St. Petersburg State University of Industrial Technologies and Design; ZAO Novbytkhim; St. Petersburg State Electrotechnical University (LETI)
Email: lusovass@mail.ru
Ресей, St. Petersburg, 191186; Gatchina, 199026; St. Petersburg, 197022
Қосымша файлдар
