Kinetics of the Reduction of Cadmium Sulfate by Thiourea Dioxide in an Aqueous Ammonia Solution upon the Metallization of Carbon Fiber


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Abstract

The kinetics of the decomposition of thiourea dioxide and the reduction of cadmium cations by thiourea dioxide in an aqueous ammonia solution are studied. The kinetic parameters of these reactions are calculated using experimental data, allowing us to adjust conditions for the synthesis of cadmium coatings on carbon fiber of grade UKN-M-12K. The presence of the metal crystalline phase on the fiber is confirmed by means of X-ray diffraction, and its amount is measured via atomic absorption spectroscopy.

About the authors

Yu. V. Polenov

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: polyurij@yandex.ru
Russian Federation, Ivanovo, 153000

E. V. Egorova

Ivanovo State University of Chemistry and Technology

Email: polyurij@yandex.ru
Russian Federation, Ivanovo, 153000

G. A. Shestakov

Ivanovo State University of Chemistry and Technology

Email: polyurij@yandex.ru
Russian Federation, Ivanovo, 153000

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