Influence of La(III) on the reactivity and sensor properties of nanocrystalline SnO2


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Synthesis of Sn(IV) and La(III) based nanocomposites has been effectuated. According to the data obtained by XRD and TPR-H2 methods, it is supposed that La in nanocompites is located in amorphous La2Sn2O7 segregation. The effect of La(III) on the adsorption properties of SnO2 surface and concentration of chemisorbed oxygen was determined. Sensor properties of obtained materials towards 10 ppm of CO in air were studied by in situ DC conductance measurements. It is shown that La introduction allows to increase sensor response of SnO2 during CO detection in air.

作者简介

V. Krivetskiy

Lomonosov Moscow State University Chemistry Department

Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

R. Rozhik

Lomonosov Moscow State University Department of Materials Science

Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

M. Rumyantseva

Lomonosov Moscow State University Chemistry Department

编辑信件的主要联系方式.
Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

N. Mordvinova

Lomonosov Moscow State University Chemistry Department

Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

A. Smirnov

Lomonosov Moscow State University Chemistry Department

Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

A. Garshev

Lomonosov Moscow State University Department of Materials Science

Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

A. Gaskov

Lomonosov Moscow State University Chemistry Department

Email: roum@inorg.chem.msu.ru
俄罗斯联邦, Moscow

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